Maxi Gomez completed the scoring following a swift Valencia counter-attack
Quique Setien suffered his first defeat as Barcelona manager as Valencia claimed their first home win over the Spanish champions since 2007.
The hosts broke the deadlock when Jordi Alba deflected Maxi Gomez's powerful strike past Marc-Andre ter Stegen.
Gomez, who had a first-half penalty saved by Ter Stegen, completed the scoring in the second half.
There were unsavoury scenes before the game as rival fans clashed outside the Mestalla Stadium.
More to follow.
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Line-ups
Match Stats
Live Text
Line-ups
Valencia
1Doménech
18Wass
24Garay
5Gabriel
14Gayá
20Torres
17CoquelinBooked at 54mins
6Kondogbia
8SolerSubstituted forSobrinoat 90'minutes
9GameiroSubstituted forRodrigoat 59'minutes
22GómezSubstituted forCostaat 80'minutes
Substitutes
3Costa
4Mangala
16Lee
19Rodrigo
23Sobrino
28Rivero
34Esquerdo
Barcelona
1ter Stegen
20Roberto
3PiquéBooked at 10mins
23UmtitiBooked at 43mins
5BusquetsBooked at 52mins
31FatiSubstituted forColladoat 85'minutes
21de JongSubstituted forRakiticat 85'minutes
8ArthurSubstituted forVidalat 56'minutes
18Alba
10Messi
17Griezmann
Substitutes
2Nélson Semedo
4Rakitic
15Lenglet
22Vidal
24Firpo
26Peña
30Collado
Referee:
Jesús Gil Manzano
Attendance:
45,882
Match Stats
Home TeamValenciaAway TeamBarcelona
Possession
Home26%
Away74%
Shots
Home7
Away14
Shots on Target
Home5
Away5
Corners
Home2
Away0
Fouls
Home13
Away16
Live Text
Posted at
Match ends, Valencia 2, Barcelona 0.
Full TimePosted at 90'+4'
Second Half ends, Valencia 2, Barcelona 0.
Posted at 90'+4'
Offside, Barcelona. Samuel Umtiti tries a through ball, but Antoine Griezmann is caught offside.
Posted at 90'+3'
Attempt saved. Lionel Messi (Barcelona) left footed shot from the left side of the box is saved in the bottom left corner. Assisted by Arturo Vidal.
Posted at 90'+2'
Attempt missed. Lionel Messi (Barcelona) left footed shot from outside the box is too high from a direct free kick.
Posted at 90'+1'
Lionel Messi (Barcelona) wins a free kick in the attacking half.
Posted at 90'+1'
Foul by Geoffrey Kondogbia (Valencia).
Posted at 90'
Foul by Samuel Umtiti (Barcelona).
Posted at 90'
Rubén Sobrino (Valencia) wins a free kick on the right wing.
SubstitutionPosted at 90'
Substitution, Valencia. Rubén Sobrino replaces Carlos Soler.
Posted at 89'
Foul by Arturo Vidal (Barcelona).
Posted at 89'
Geoffrey Kondogbia (Valencia) wins a free kick in the defensive half.
Posted at 87'
Attempt blocked. Ivan Rakitic (Barcelona) left footed shot from the centre of the box is blocked.
Posted at 86'
Attempt saved. Lionel Messi (Barcelona) left footed shot from outside the box is saved in the bottom right corner. Assisted by Ivan Rakitic.
SubstitutionPosted at 85'
Substitution, Barcelona. Álex Collado replaces Ansu Fati.
SubstitutionPosted at 85'
Substitution, Barcelona. Ivan Rakitic replaces Frenkie de Jong.
Posted at 81'
Corner, Valencia. Conceded by Samuel Umtiti.
Posted at 80'
Offside, Valencia. Jaume Costa tries a through ball, but Ferrán Torres is caught offside.
SubstitutionPosted at 80'
Substitution, Valencia. Jaume Costa replaces Maxi Gómez.
Posted at 79'
Foul by Sergio Busquets (Barcelona).
Posted at 79'
Carlos Soler (Valencia) wins a free kick in the attacking half.
Goal!Posted at 77'
Goal! Valencia 2, Barcelona 0. Maxi Gómez (Valencia) right footed shot from the centre of the box to the bottom right corner. Assisted by Ferrán Torres.
Posted at 76'
Foul by Sergi Roberto (Barcelona).
Posted at 76'
José Gayá (Valencia) wins a free kick in the defensive half.
Posted at 76'
Samuel Umtiti (Barcelona) wins a free kick in the defensive half.
Posted at 76'
Foul by Rodrigo Moreno (Valencia).
Posted at 73'
Attempt saved. Lionel Messi (Barcelona) left footed shot from outside the box is saved in the bottom right corner.
Posted at 72'
Antoine Griezmann (Barcelona) wins a free kick in the attacking half.
Posted at 72'
Foul by Ezequiel Garay (Valencia).
Posted at 71'
Sergio Busquets (Barcelona) wins a free kick in the defensive half.
Posted at 71'
Foul by Maxi Gómez (Valencia).
Posted at 70'
Attempt missed. Lionel Messi (Barcelona) header from the centre of the box is close, but misses to the right. Assisted by Antoine Griezmann with a cross.
Posted at 68'
Foul by Arturo Vidal (Barcelona).
Posted at 68'
Maxi Gómez (Valencia) wins a free kick on the right wing.
Posted at 68'
Attempt missed. Lionel Messi (Barcelona) left footed shot from the left side of the box is just a bit too high. Assisted by Jordi Alba.
Posted at 63'
Foul by Sergi Roberto (Barcelona).
Posted at 63'
Rodrigo Moreno (Valencia) wins a free kick in the defensive half.
Posted at 60'
Foul by Arturo Vidal (Barcelona).
Posted at 60'
Francis Coquelin (Valencia) wins a free kick in the defensive half.
SubstitutionPosted at 59'
Substitution, Valencia. Rodrigo Moreno replaces Kevin Gameiro.
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goal
Source: bbc.com