Lionel Messi made his 75th appearance in the Copa del Rey - equalling the club record held by Josep Samitier
Barcelona's hopes of reaching a seventh successive Copa del Rey final have ended at the quarter-final stage with defeat by Athletic Bilbao.
The tight contest was decided in the third minute of stoppage time when Spanish forward Inaki Williams headed past Marc-Andre ter Stegen.
Barcelona captain Lionel Messi wasted a good late chance when he fired at the legs of Athletic goalkeeper Unai Simon.
There was another cup shock earlier when Real Madrid lost to Real Sociedad.
It means for the first time since 2010, the Copa del Rey final will feature neither Barcelona nor Real.
The two surprise results come a day after second-tier side Mirandes defeated Villarreal 4-2. Granada, who overcame Valencia 2-1, make up the semi-final line-up.
-
Line-ups
Match Stats
Line-ups
Ath Bilbao
1Simón
5ÁlvarezBooked at 44mins
3Núñez
4Martínez
21Capa
14García CarrilloBooked at 63mins
16VesgaBooked at 53minsSubstituted forSan Joséat 66'minutes
17Berchiche Izeta
22GarcíaSubstituted forGómezat 89'minutes
10MuniainSubstituted forAdurizat 77'minutes
9Williams
Substitutes
6San José
12Larrazabal
15Lekue
19Gómez
20Aduriz
25Villalibre
31Ezkieta
Barcelona
1ter Stegen
2Nélson SemedoBooked at 6mins
3PiquéBooked at 72minsSubstituted forUmtitiat 80'minutes
15Lenglet
18AlbaBooked at 40mins
21de JongBooked at 57mins
5Busquets
4RakiticSubstituted forArthurat 69'minutesBooked at 81mins
20Roberto
10MessiBooked at 39mins
31FatiSubstituted forGriezmannat 57'minutes
Substitutes
8Arthur
17Griezmann
22Vidal
23Umtiti
24Firpo
26Peña
30Collado
Referee:
Juan Martínez Munuera
Attendance:
49,154
Match Stats
Home TeamAth BilbaoAway TeamBarcelona
Possession
Home32%
Away68%
Shots
Home7
Away11
Shots on Target
Home1
Away5
Corners
Home3
Away4
Fouls
Home15
Away13
Source: bbc.com